Nope, I think my vote goes to Pokemon: The Power of One, not only does Misty almost confess that she's in love with Ash, but we also get two epic Team Rocket scenes--one where Team Rocket--Jessie, James, and Meowth, selflessly risk their lives to save Ash and Lugia, and the other, at the end, where Slowking congratulates them on their heroism and points out that they're on TV! Team Rocket then argue about the prospect of becoming good guys. :)